Here's another one for the meteorologists, cryophysicists and conspiracy theorists.

Discussion in 'Bulletin Board ARCHIVE' started by *Windy, Feb 6, 2009.

  1. *Windy

    *Windy Banned Idiot

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    </p>

    The walkway around the pitch is frozen as well. Get stuck into that.</p>
     
  2. Spa

    Spartacus Well-Known Member

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    Is it?

    salt?
    Grit?
    Elbow grease and a shovel?

    Who's feeding you the ******** in any case??

    No desire for the game to go ahead.
     
  3. *Windy

    *Windy Banned Idiot

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    RE: Is it?

    Surface permeating salt and grit? You want to invent that mate, you'll make a fortune.</p>

    I'm being fed the &quot;********&quot; by someone who's actually seen the inside of the ground today and hasa fecking cluewhat they're on about. Where are your assertions originating?</p>

    You don't have to get a sandy vagina by the way. The game will happen. Who knows? We might have fewer injuries by then.</p>
     
  4. Spa

    Spartacus Well-Known Member

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    Surface permeating what?

    Have they invented shovel / rock salt proof snow / ice? And for that matter I've seen very little ice anywhere.

    FFS

    I will reiterate...there was either no desire at the club(s) for the match to go ahead or incompetence in stadium management.
     
  5. Spa

    Spartacus Well-Known Member

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  6. Spa

    Spartacus Well-Known Member

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    meteorology..Its sunny and has been since yesterday morning. nt
     
  7. Spa

    Spartacus Well-Known Member

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    Why does salt melt ice....

    Home :FAQ :Solutions Print | Comment
    Previous Question Next Question

    Why does salt melt ice?


    Vocabulary
    equilibrium*
    eutectic mixture*
    freezing point depression*
    melting point*
    phase diagram*
    solute*
    (Note: If you're already familiar with chemical potentials, you may be interested in this alternative thermodynamic explanation.)

    Two things happen when ice and water are placed in contact:

    * Molecules on the surface of the ice escape into the water (melting), and
    * molecules of water are captured on the surface of the ice (freezing).

    When the rate of freezing is the same as the rate of melting, the amount of ice and the amount of water won't change on average (although there are short-term fluctuations at the surface of the ice). The ice and water are said to be in dynamic equilibrium with each other. The balance between freezing and melting can be maintained at 0°C, the melting point of water, unless conditions change in a way that favors one of the processes over the other.


    If you don't see the animation above, a nonanimated version is available; or you can download the free Flash plugin from Macromedia.
    The balance between freezing and melting processes can easily be upset. If the ice/water mixture is cooled, the molecules move slower. The slower-moving molecules are more easily captured by the ice, and freezing occurs at a greater rate than melting. You can see a demonstration of this by clicking on the temperature in the animation and setting it to a lower value (say, -10).

    Conversely, heating the mixture makes the molecules move faster on average, and melting is favored. Reset the animation and then enter a higher value for the temperature (say 10) and watch what happens.

    Adding salt to the system will also disrupt the equilibrium. Consider replacing some of the water molecules with molecules of some other substance. The foreign molecules dissolve in the water, but do not pack easily into the array of molecules in the solid. Try hitting the "Add Solute" button in the animation above. Notice that there are fewer water molecules on the liquid side because the some of the water has been replaced by salt. The total number of waters captured by the ice per second goes down, so the rate of freezing goes down. The rate of melting is unchanged by the presence of the foreign material, so melting occurs faster than freezing.

    That's why salt melts ice.

    To re-establish equilibrium, you must cool the ice-saltwater mixture to below the usual melting point of water. For example, the freezing point of a 1 M NaCl solution is roughly -3.4°C. Solutions will always have such a freezing point depression. The higher the concentration of salt, the greater the freezing point depression [1].

    But won't any foreign substance cause a freezing point depression, according to this model? Yes! For every mole of foreign particles dissolved in a kilogram of water, the freezing point goes down by roughly 1.7-1.9°C. Sugar, alcohol, or other salts will also lower the freezing point and melt the ice. Salt is used on roads and walkways because it is inexpensive and readily available.

    It is important to realize that freezing point depression occurs because the concentration of water molecules in a solution is less than the concentration in pure water. The nature of the solute doesn't matter. One might expect from the diagram above that solutes with large molecules are better at blocking water molecules travelling towards the surface of the ice. The hypothesis that solutes with large molecules cause a larger freezing point depression than those with smaller molecules is not in accord with experimental data! The misconception arises because the diagram can't be drawn to scale; the size of the molecules is very small compared to the distance between them.

    Saltwater phase diagram
    Phase map for salt water. Drawn from a diagram by R. E. Dickerson (Note 3)
    As ice begins to freeze out of the salt water, the fraction of water in the solution becomes lower and the freezing point drops further. This does not continue indefinitely, because eventually the solution will become saturated with salt. The lowest temperature possible for liquid salt solution is -21.1°C. At that temperature, the salt begins to crystallize out of solution (as NaCl·2 H2O), along with the ice, until the solution completely freezes. The frozen solution is a mixture of separate NaCl·2H2O crystals and ice crystals, not a homogeneous
     
  8. Spa

    Spartacus Well-Known Member

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  9. *Windy

    *Windy Banned Idiot

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    RE: Surface permeating what?

    </p>

    Are you aware of what the track's made of? Do you think ice always sits on top? You're talking complete ballocks mate.</p>

    </p>
     
  10. *Windy

    *Windy Banned Idiot

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    The basturds! Fancy wanting to win the game!

    </p>

    </p>
     
  11. *Windy

    *Windy Banned Idiot

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    Somebody should tell the ice on the stands.

    </p>

    Did I tell you there's ice on the stands?</p>
     
  12. *Windy

    *Windy Banned Idiot

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    Now all you have to do is invent a way of injecting it into the track.

    </p>

    Did you think it was tarmac?</p>

    &quot;FFS&quot;</p>
     
  13. Spa

    Spartacus Well-Known Member

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    Re: Here's another one for the metts, cryophysicists and conspiracy theorists. nt
     
  14. Spa

    Spartacus Well-Known Member

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    I've got no problem with that nt
     
  15. Spa

    Spartacus Well-Known Member

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    Red herring that one don nt
     
  16. Spa

    Spartacus Well-Known Member

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    Ice on the stands??

    There's none on my house nor the surrounding houses in the intervening 300 yards between me and the hypothetical offending article.

    Can see very little evidence of such a manifestation from here.
     
  17. Spa

    Spartacus Well-Known Member

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    pff

    red herring.
     

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